Guide Electrostatic and Stereoelectronic Effects in Carbohydrate Chemistry

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  2. ISBN 13: 9781461498254
  3. Electrostatic and Stereoelectronic Effects in Carbohydrate Chemistry | Momcilo Miljkovic | Springer

Pickup not available. This book deals with polar effects in carbohydrates and how these effects control the stereochemistry of carbohydrate reactions. About This Item We aim to show you accurate product information.

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  1. Momcilo Miljkovic (Author of Carbohydrates).
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In: Advances in Carbohydrate Chemistry and Biochemistry. Derek H, editor. Academic; J Am Chem Soc. Org Lett. J Mol Struct.

ISBN 13: 9781461498254

J Org Chem. Details of stereochemical proofs are provided as supporting information.


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Stevens RV. Acc Chem Res.

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Hagen G, Mayr H. Attempts to locate the transition state structures for these reactions were unsuccessful. Details are provided as supporting information. Whitfield DM. Adv Carb Chem Biochem. Angew Chem Int Ed. Groenewald F, Dillen J. Struct Chem.

Stereoelectronic Effects

Details of all computational studies are provided as supporting information. Calculations indicate that the equatorial oxocarbenium ion 3 is favored over the axial conformer by 2. In cases where the nucleophile approaches a substituent closely, such as C2-substituted systems, transition state effects can be important see, for example, reference 8. In 4 , transannular interactions occur between the nucleophile and two hydrogen atoms of the ring.

The distance between the carbon atom of Nu and H3 is 2. In 5 , there is only one transannular interaction with H6 , and the distance is 2. A model assuming that selectivity is controlled by attack trans to the axial hydrogen atom at C3 would not be consistent with the models used to explain selectivities in five- and six-membered ring systems references 9 and Computational studies also suggest that attack by mode B should be favored. A methyl group was used as the carbon nucleophile to simplify the calculation.

The twist-chair isomer 5 was found to be lower energy than 4 by 4. Established seller since Seller Inventory IQ More information about this seller Contact this seller 1. Published by Belgrade About this Item: Belgrade, Soft Cover. Condition: Good.

Electrostatic and Stereoelectronic Effects in Carbohydrate Chemistry | Momcilo Miljkovic | Springer

Soft cover in good condition. Some creasing and discolouration to covers, internally clean, binding is tight. Poetry, in Serbian. Seller Inventory More information about this seller Contact this seller 2. Shipped from US within 10 to 14 business days. More information about this seller Contact this seller 3. Published by Editions l'Age d'Homme About this Item: Editions l'Age d'Homme, Condition: D'occasion - Comme Neuf. Seller Inventory LP 32 More information about this seller Contact this seller 4. Published by Transition About this Item: Transition, Couverture souple.

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Seller Inventory PAZ More information about this seller Contact this seller 6. Published by Centre culturel de la R. Oto Denes.